Estimating Diffusion Coefficients From Count Data: Einstein-Smoluchowski Theory Revisited

The problem of estimating diffusion coefficients has been considered extensively in both discrete and continuous time. We consider here an approach based on counting occupation numbers of diffusing particles. The problem, and our approach, are motivated by statistical mechanics.     

光纤传感器低温啁啾现象的分析

介绍了光纤光栅传感原理,依据传感机理制作了两种结构材料的光纤光栅传感器,对它们进行了试验,将试验后的传感数据进行了拟合分析和比对,并对它们在低温环境下产生的啁啾现象进行了分析,验证了采用预拉工艺对解决啁啾现象的可行性。     

Observation of field induced anomalous quantum criticality in Ce0.6Y0.4NiGe2 compound

We report the results of our investigation of magnetization and heat capacity on a series of compounds Ce${}_{1?x}$Y_xNiGe₂ ($x=0.1,0.2\text{ and }0.4$) under the influence of external magnetic field. Our studies of the thermodynamic quantity $?\mathrm{d}M/\mathrm{d}T$ on these compounds indicate that magnetic frustration persists in Ce_0.9Y_0.1NiGe₂, as also reported for the parent compound CeNiGe₂. The weak signature of this frustration is also noted in Ce_0.8Y_0.2NiGe₂, whereas, it is suppressed in Ce_0.6Y_0.4NiGe₂. Heat capacity studies on Ce_0.9Y_0.1NiGe₂ and Ce_0.8Y_0.2NiGe₂ indicate the presence of a new magnetic anomaly at high field which indicates that quantum criticality is absent in these compounds. However, for Ce_0.6Y_0.4NiGe₂ such an anomaly is not noted. For this later compound, the magnetic field (H) and temperature (T) dependence of heat capacity and magnetization obey $H/T$ scaling above critical fields. However, the obtained scaling critical parameter (δ) is 1.6, which is away from mean field value of 3. This deviation suggests the presence of unusual fluctuations and anomalous quantum criticality in these compounds. This unusual fluctuation may arise from disorderness induced by Y-substitution.     

Analysis on First-stage Ignition of n-Heptane at Low Temperatures with a Lumped Skeletal Mechanism

Two-stage ignition exists in the low-temperature combustion process of n-heptane and the first-stage ignition also shows a negative temperature coefficient(NTC) phenomenon. To study key reactions and understand chemical principles affecting the first-stage ignition of n-heptane, a lumped skeletal mechanism with 62 species is obtained based on the detailed NUIGMech1.0 mechanism using the directed relation graph method assisted by sensitivity analysis and isomer lumping. The lumped mechanism shows good performance on ignition delay time under wide conditions. The study revealed that the temperature after the first-stage ignition is higher and a larger amount of fuel is consumed at lower initial temperatures. The temperature at the first-stage ignition is relatively insensitive to the initial temperature. Further sensitivity analysis and reaction path analysis carried out based on the lumped mechanism show that the decomposition of RO₂ to produce alkene and HO₂is the most important reaction to inhibit the first-stage ignitions. The chain branching explosion closely related to the first-stage ignition will be terminated when the rate constant for the RO₂ decomposition is larger than that of the isomerization of RO₂ to produce QOOH. The NTC behavior as well as other characteristics of the first-stage ignition can be rationalized from the competition between these two reactions.     

Trefftz法中的自锁现象及变量减缩法

用Trefftz型边界解法分析了中厚板弯曲问题,发现了一类新的、因Trefftz函数溢机引起的“自锁现象”,并提出了一种消除这类自锁问题的“变量减缩法”。     

高精度非线性格式WCNS的分析研究与其应用

首先将Fourier方法推广于高维方向研究了五阶精度WCNS的特性,并与其他高阶格式进行比较。分析结果表明WCNS的高精度特性普遍接近甚至好于迎风偏置五阶显式格式EUW-5与Pade′标准格式。然后开展了WCNS的应用研究,采用高效率的WCNS-E-5数值模拟了含强激波的高维复杂流场。算例包括二维高超声速边界层对自由流扰动波的吸收问题以及三维球头绕流问题。计算结果反映出WCNS-E-5对激波等间断的良好捕捉能力,图像清晰光滑,数据准确可靠。     

Point-source spark shadowgraphy at the historic birthplace of supersonic transportation

About a decade after its foundation, the most advanced ballistics laboratory in Germany at the time, the Kruppsche Schiessplatz, was utilized by Ernst Mach in 1888. His intent was to validate his pioneering shock wave research using military shells as supersonic vehicles. The 125th anniversary of the Schiessplatz was celebrated in 2002. Along with Machs research, it served to initiate the field of supersonic transportation technology. The specific subject of this paper is the application of point-source spark shadowgraphy at the same laboratory in the 1970s to visualize gas flow over aeroballistic projectiles. However, different from Machs original interest, the new purpose of spark photography at that time in the ballistic ranges of the German Bundeswehr was to find technical solutions to aeroballistic problems when field-testing gave incomplete answers. Both a qualitative and a quantitative understanding of the principles of aeroballistics were sought in this research.Received: 3 February 2003, Accepted: 30 June 2003, Published online: 2 September 2003An abridged version of this paper was presented at the 13th American Physical Society Topical Conference on Shock Compression of Condensed Matter at Portland, Oregon, from July 20 to 25, 2003     

Energy Transfers in a System of Two Coupled Oscillators with Essential Nonlinearity: 1:1 Resonance Manifold and Transient Bridging Orbits

The purpose of this study is to highlight and explain the vigorous energy transfers that may take place in a linear oscillator weakly coupled to an essentially nonlinear attachment, termed a nonlinear energy sink. Although these energy exchanges are encountered during the transient dynamics of the damped system, it is shown that the dynamics can be interpreted mainly in terms of the periodic orbits of the underlying Hamiltonian system. To this end, a frequency-energy plot gathering the periodic orbits of the system is constructed which demonstrates that, thanks to a 1:1 resonance capture, energy can be irreversibly and almost completely transferred from the linear oscillator to the nonlinear attachment. Furthermore, it is observed that this nonlinear energy pumping is triggered by the excitation of transient bridging orbits compatible with the nonlinear attachment being initially at rest, a common feature in most practical applications. A parametric study of the energy exchanges is also performed to understand the influence of the parameters of the nonlinear energy sink. Finally, the results of experimental measurements supporting the theoretical developments are discussed. This study was carried out while the author was a postdoctoral fellow at the National Technical University of Athens and at the University of Illinois at Urbana-Champaign.     

Plasma mitigation of shock wave: experiments and theory

Two types of plasma spikes, generated by on-board 60 Hz periodic and pulsed dc electric discharges in front of two slightly different wind tunnel models, were used to demonstrate the non-thermal plasma techniques for shock wave mitigation. The experiments were conducted in a Mach 2.5 wind tunnel. (1) In the periodic discharge case, the results show a transformation of the shock from a well-defined attached shock into a highly curved shock structure, which has increased shock angle and also appears in diffused form. As shown in a sequence with increasing discharge intensity, the shock in front of the model moves upstream to become detached with increasing standoff distance from the model and is eliminated near the peak of the discharge. The power measurements exclude the heating effect as a possible cause of the observed shock wave modification. A theory using a cone model as the shock wave generator is presented to explain the observed plasma effect on shock wave. The analysis shows that the plasma generated in front of the model can effectively deflect the incoming flow; such a flow deflection modifies the structure of the shock wave generated by the cone model, as shown by the numerical results, from a conic shape to a curved one. The shock front moves upstream with a larger shock angle, matching well with that observed in the experiment. (2) In the pulsed dc discharge case, hollow cone-shaped plasma that envelops the physical spike of a truncated cone model is produced in the discharge; consequently, the original bow shock is modified to a conical shock, equivalent to reinstating the model into a perfect cone and to increase the body aspect ratio by 70%. A significant wave drag reduction in each discharge is inferred from the pressure measurements; at the discharge maximum, the pressure on the frontal surface of the body decreases by more than 30%, the pressure on the cone surface increases by about 5%, whereas the pressure on the cylinder surface remains unchanged. The energy saving from drag reduction is estimated to make up two-thirds of the energy consumed in the electric discharge for the plasma generation. The measurements also show that the plasma effect on the shock structure lasts much longer than the discharge period.

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Direct analysis of anabolic steroids in urine using Leidenfrost phenomenon assisted thermal desorption-dielectric barrier discharge ionization mass spectrometry

Rapid detection of trace level anabolic steroids in urine is highly desirable to monitor the consumption of performance enhancing anabolic steroids by athletes. The present article describes a novel strategy for identifying the trace anabolic steroids in urine using Leidenfrost phenomenon assisted thermal desorption (LPTD) coupled to dielectric barrier discharge (DBD) ionization mass spectrometry. Using this method the steroid molecules are enriched within a liquid droplet during the thermal desorption process and desorbed all-together at the last moment of droplet evaporation in a short time domain. The desorbed molecules were ionized using a dielectric barrier discharge ion-source in front of the mass spectrometer inlet at open atmosphere. This process facilitates the sensitivity enhancement with several orders of magnitude compared to the thermal desorption at a lower temperature. The limits of detection (LODs) of various steroid molecules were found to be in the range of 0.05–0.1 ng mL⁻¹ for standard solutions and around two orders of magnitude higher for synthetic urine samples. The detection limits of urinary anabolic steroids could be lowered by using a simple and rapid dichloromethane extraction technique. The analytical figures of merit of this technique were evaluated at open atmosphere using suitable internal standards. The technique is simple and rapid for high sensitivity and high throughput screening of anabolic steroids in urine.